Due to global greenhouse gas emissions, the atmospheric carbon dioxide level has risen to over 400 ppm, an increase of over 100 ppm from just 60 years ago. Post-combustion carbon capture and sequestration methods have been shown to be useful in stemming this rise in carbon dioxide emissions however the current separation methods/materials are inadequate due to toxicity and cost. Powerplant flue-gas has low partial-pressures of carbon dioxide, compared to that of nitrogen, which makes finding a material that selectively captures carbon dioxide at low partial pressures essential to making a great adsorbent material. We will prepare and post-synthetically modify different porous adsorbents in the form of metal-organic frameworks (MOFs) and zeolites to better capture and separate carbon dioxide. Post-synthetic methods will involve the polymerization of amines and epoxides into MOF/zeolite materials whose stability, structure, and gas adsorption properties will be characterized. Depending on interest, a non-synthetic fully computational project looking at the carbon dioxide adsorption in MOFs via state-of-the-art solid-state modeling software may be considered. No prior experience in solid-state synthesis, computational chemistry, or materials chemistry are needed or expected. Students interested in these research opportunities should reach out and discuss this further with Professor Hudson.
Successful completion of CHEM 102 or CHEM 111
Number of Student Researchers
Applications open on 01/03/2021 and close on 03/22/2021